Concert For Ukraine line-up: Ed Sheeran, Camila Cabello and Anne-Marie performing tonight

Ed Sheeran and Camila Cabello will perform at a Ukraine fundraiser (Getty)
Ed Sheeran and Camila Cabello will perform at a Ukraine fundraiser (Getty)

Ed Sheeran, Camila Cabello and Anne-Marie are among the acts set to headline tonight's charity event Concert For Ukraine.

They will be joined by Emeli Sande, Gregory Porter and Snow Patrol at the fundraising gig, which will take place at the Resorts World Arena in Birmingham and air live on ITV tonight (Tuesday) at 8pm.

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Also taking to the stage are Paloma Faith, Nile Rodgers & Chic, Becky Hill, The Kingdom Choir, Manic Street Preachers and Tom Odell.

British singer Anne-Marie Rose Nicholson aka Anne-Marie poses on the red carpet upon her arrival for the BRIT Awards 2022 in London on February 8, 2022. - RESTRICTED TO EDITORIAL USE  NO POSTERS  NO MERCHANDISE NO USE IN PUBLICATIONS DEVOTED TO ARTISTS (Photo by Niklas HALLE'N / AFP) / RESTRICTED TO EDITORIAL USE  NO POSTERS  NO MERCHANDISE NO USE IN PUBLICATIONS DEVOTED TO ARTISTS (Photo by NIKLAS HALLE'N/AFP via Getty Images)
Anne-Marie is one of the headline acts. (AFP) (NIKLAS HALLE'N via Getty Images)

The show is set to be hosted by Roman Kemp, Marvin Humes and Emma Bunton.

Cabello said: “My heart is breaking for the people of Ukraine. As refugees from Ukraine join millions of other displaced people around the globe, we all have a responsibility. One of the biggest needs is to get funds to organisations who can serve these communities directly, so we’re focusing our efforts on doing that as quickly as we can.”

Read more: Ed Sheeran denies 'borrowing' music as he takes stand in copyright dispute

Russian president Vladimir Putin began his military invasion of Ukraine on 24 February. Cities in the country have suffered mass destruction and hundreds of thousands of Ukrainians have fled the country.

LONDON, ENGLAND - JUNE 12:  Camila Cabello performs live at Brixton Academy on June 12, 2018 in London, England.  (Photo by Samir Hussein/Redferns)
Camila Cabello said her heart is breaking for the people of Ukraine. (Getty Images) (Samir Hussein via Getty Images)

Sheeran - who is currently caught up in a copyright lawsuit at the High Court over his song 'Shape Of You' - did not release a statement.

Sande commented: “I will be singing to try to help every human being forced to flee their home and in solidarity with those being racially discriminated against even within this humanitarian crisis. Nobody should be refused access to relief, aid and the right to cross the border to safety, and I’m pleased for the chance to support the DEC’s appeal to help all people whose lives have been affected by the conflict.”

MARCH 7th 2022: Ed Sheeran denies copyright claim at High Court trial in London and testified that he did not
Ed Sheeran will perform at Concert For Ukraine, airing live on ITV. (AP) (zz/Dennis Van Tine/STAR MAX/IPx)

And Gregory Porter added: "So thankful to be able to raise my voice in the chorus of peace. Together we can show our support for those that are sadly affected by the current world's events.”

The broadcast will combine musical performances with short films recognising the ongoing relief efforts and the difficulties faced by those affected by the conflict.

Emily Sande performing on the Other Stage at Glastonbury Festival, at Worthy Farm in Somerset. (Photo by Ben Birchall/PA Images via Getty Images)
Emily Sande will sing at the Concert For Ukraine live on ITV. (Getty Images) (Ben Birchall - PA Images via Getty Images)

Viewers will be invited to donate money to the DEC [Disasters Emergency Committee] Ukraine Humanitarian Appeal throughout the two hour evening show.

All sponsorship and advertising revenue generated from the broadcast – estimated to be more than £3 million – will also be donated to the DEC appeal.

Gary Lightbody and Johnny McDaid from Snow Patrol perform live on Day 2 of the Isle of Wight Festival 2021, Seaclose Park, Newport, Isle of Wight . Picture date: Saturday 18th September 2021. Photo credit should read: David Jensen/EMPICS Entertainment
Snow Patrol will perform at the charity fundraiser in Birmingham. (PA) (EMPICS Entertainment)

Concert For Ukraine will be broadcast on ITV, STV, ITV Hub and STV Player.

ITV has previously supported DEC appeals including for the Afghanistan crisis in December 2021.

Concert for Ukraine airs at 8pm tonight (Tuesday) on ITV.

Watch: Ed Sheeran recently took the witness stand in a copyright lawsuit